This will likely be rejected for one the same reasons that they decided they would not add any new flag emojis. Flags come and go. Bitcoin hasn't even been around for 20 years yet, and its future is highly uncertain.
Also, considered as a currency, it would be better as a regular text character, not an emoji. Like $, €, ¥, £, etc.
I don't know about strictly "unable" but there are a million contexts where it is a bad idea and simply not done. Like a spreadsheet or financial document. Or anywhere you want your text to behave like text — with a consistent font, color, style, etc. The difference between $ (text) and 💲 (emoji) is pretty stark in most contexts.